Liquid metals and their hybrids as smart electronic materials--by Long Ren
The future of electronics is believed to be soft, elastomeric, miniaturized, and biocompatible. Exploration of soft and biocompatible electronic materials that respond to the environmental changes and manifest their own functions according to the optimum conditions will undoubtedly be an essential task in the development of smart materials and the smart electronic system. Conventional, rigid materials including stiffness metal and dielectric ceramics remain the key electronic building blocks of most modern smart electronic devices, but show limited abilities towards to the soft smart electronics. Among the large number of smart materials, the term “soft” is well presented by the field-responsive fluids that typically divided into magnetorheological fluids and electrorheological fluid. However, the fluids carriers used in these smart fluids are usually non-conductive, being the barrier for the smart electronics.
The re-emergence of room temperature liquid metals (LMs) presents an exciting paradigm for an ideal combination of metallic and fluidic properties. The unique fluid metal features of non-hazardous Ga-based LMs, including high surface energy, low viscosity, electrical and thermal conductivity, a wide temperature range of the liquid state, and desirable chemical activity for many applications, have led to remarkable possibilities for harnessing their properties and achieving unique functionalities. The realization of their stimulus-responsivity and multi-functionality make Ga-based LMs an attractive family of ‘smart materials’ that could act as the basis of countless applications in new frontiers, covering a wide range from materials science and engineering to medicine. Constructing hybrids of Ga-based LMs with other functional materials can further extend the field-responsive capacity of liquid metals to incredible levels.
We have already done some works on preparation of LM nanostructures and investigation of the related physical and chemical properties. We have also studied Ga-based LMs’ stimulus-responsive behaviors and developed the corresponding potential devices with liquid metal-based nanodroplets and hybrids, including developing superconductive LM nanodroplets for printable superconducting electronics, mechanical adaptable LM bio-electrodes, and photo-response flexible electronics. Further exploration will be focused on photo-/electro-/thermal- induced LMs’ stimulus-responsive behaviors, and applying to the fields ranging from catalysis, energy storage, sensors, and bio-devices. There is a long way to go for advancing LM-based smart materials that can be nearly as good as the one shown in the ‘Terminator’ movie series. The aim of our research in this field is not to make the science-fiction fact, but once similar achievements have been made, revolutionary advances in materials science, as well as ubiquitous applications relevant to electronics, optics, materials science, chemistry, and medicine can be gained.